In situ speciation studies of copper in the electroplating sludge under an electric field.
نویسندگان
چکیده
Speciation of copper in the electrokinetic treatments of an industrial sludge was studied by in situ extended X-ray absorption fine structural (EXAFS) and X-ray absorption near-edge structural (XANES) spectroscopies in the present work. The least-square fits (LSF) of the XANES spectra indicated that the main copper species in the sludge were Cu(NO)(3) (82%) and adsorbed copper (Cu/SiO(2)) (17%). Copper in the sludge possessed a Cu-O bond distance of 1.97A with a coordination number (CN) of 3.8. In the second shells, the bond distance of Cu-(O)-Si was 3.03A with a CN of 1.5. Most of Cu/SiO(2) was dissolved in the aqueous phase since little Cu-(O)-Si species in the sludge was found after 180 min of the electrokinetic treatments. About 69% of total Cu(II) was dissolved into the aqueous phase and 51% of which was migrated to the cathode under the electric field (5V cm(-1)) for 180 min.
منابع مشابه
Fate of zinc in an electroplating sludge during electrokinetic treatments.
Chemical structure of zinc in the electrokinetic treatments of an electroplating sludge has been studied by in situ extended X-ray absorption fine structural (EXAFS) and X-ray absorption near edge structural (XANES) spectroscopies in the present work. The least-square fitted XANES spectra indicate that the main zinc compounds in the sludge were ZnCO(3) (75%), ZnOSiO(2) (17%) and Zn(OH)(2) (7%)....
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ورودعنوان ژورنال:
- Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy
دوره 60 10 شماره
صفحات -
تاریخ انتشار 2004